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These Raman peaks are mostly caused by the low crystal symmetry and are linked to fundamental Raman modes(A1g, E2g, And as well E1g) Coupled together and to acoustic phonons. The two most bold Raman peaks are at 163 and 213cm1, Respectively, And match the in plane(E2g) And mostly due to plane(A1g such) Moaning modes(Second Fig.
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